PACKAGING ARTICLE COMPRISING AN ENVELOPE AND ANHYDROUS COMPOSITION COMPRISING AN OXIDIZING AGENT

专利摘要:
The present invention relates to a packaging article comprising i) an envelope defining at least one cavity, the envelope comprising water-soluble and / or fat-soluble fibers, preferably water-soluble fibers; ii) at least one anhydrous oxidizing composition, preferably in the form of a paste or a powder, comprising at least one anhydrous chemical oxidizing agent, preferably in the form of a paste or a powder; it being understood that the oxidizing composition is in one of the cavities defined by the envelope i).
公开号:FR3016288A1
申请号:FR1363394
申请日:2013-12-23
公开日:2015-07-17
发明作者:Fabien Aubert；Frederic Guerin
申请人:LOreal SA；
IPC主号:

专利说明:

[0001] The present invention relates to a packaging article comprising an anhydrous chemical oxidizing agent for dyeing and / or bleaching keratinous fibers, in particular human hair. In cosmetics, in the fields of dyeing, bleaching and permanent deformation of keratinous fibers, and in particular human keratin fibers such as the hair, oxidizing compositions are used. Thus, in oxidation dyeing of the hair, oxidizing compositions are mixed with the oxidation dyes (bases and couplers), which are colorless by themselves, to generate colored and coloring compounds by a process of oxidative condensation. Oxidizing compositions are also used in the direct dyeing of hair mixed with certain direct dyes which are colored and dyed to obtain a coloration with a lightening effect of the hair. Among the oxidizing agents conventionally used for dyeing keratinous fibers, mention may be made of hydrogen peroxide or compounds capable of producing hydrogen peroxide by hydrolysis, such as urea peroxide. Persals such as perborates and persulfates can also be used. In hair discoloration, the bleaching compositions contain one or more oxidizing agents. Among these oxidizing agents, the most conventionally used are hydrogen peroxide or compounds capable of producing hydrogen peroxide by hydrolysis, such as urea peroxide or persalts such as perborates, percarbonates and persulfates, hydrogen peroxide and persulfates being particularly preferred. These compositions may be aqueous compositions containing alkaline agents (amines or ammonia) which are diluted at the time of use with an aqueous hydrogen peroxide composition. These compositions may also be formed from anhydrous products, which are powders or pastes, which contain alkaline compounds (amines and / or alkali silicates), and a peroxygenated reagent such as persulfates, perborates or percarbonates, ammonium or alkali metals, which are diluted at the time of use with an aqueous composition of hydrogen peroxide.
[0002] Bleaching powders, however, tend to form dust during handling, transport and storage. However, the products that compose them (persulfates, alkali silicates) are aggressive and in particular irritating to the eyes, the respiratory tract and the mucous membranes.
[0003] In order to overcome the volatility problem of bleaching powders, less volatile powders have been developed by adding additives making it possible to reduce the level of fine particles and pastes which comprise the said pulverulent agents (peroxygenated salts, alkaline agents, thickeners) in an organic inert liquid carrier. However, these less volatile powders and pastes may be less effective than simple starting powders. Pasta, as well as powders, nevertheless require certain precautions when handling, especially when it comes to weigh them to mix with the oxidizing composition, to avoid staining clothes. In addition, it is sought to improve the ease of mixing and application of coloring or bleaching compositions in the form of powder or paste, which is mixed at the time of use with the aqueous oxidizing composition. The object of the present invention is to provide an article for the treatment of keratinous fibers, in particular for the dyeing and / or bleaching of keratinous fibers, which makes it possible to solve the problems, in particular of manipulation, of compositions known in the art prior art, by providing an article comprising an envelope and an anhydrous oxidizing composition. This article avoids handling problems related to the volatility of powders or weighing problems by proposing a ready-to-use product without a dosage step. It also makes it possible to improve the resistance of the oxidizing composition to temperature variations, and in particular makes it possible to avoid the problem of destabilization during storage at low temperatures and during transport including temperature cycles. It also prevents loss of lightening power.
[0004] Another object of the present invention is to provide oxidizing compositions of keratinous fibers which are easy to mix and apply, in particular which allow a homogeneous distribution of the composition on the hair. This object (s) is (are) achieved by the present invention which relates to a packaging article comprising: i) an envelope defining at least one cavity, the envelope comprising water-soluble fibers and / or liposoluble, preferably water-soluble fibers; ii) at least one anhydrous oxidizing composition, preferably in the form of a paste or a powder, comprising at least one anhydrous chemical oxidizing agent, preferably in the form of a paste or a powder; it being understood that the oxidizing composition is in one of the cavities defined by the envelope i).
[0005] Another subject of the invention is a process for treating keratinous fibers, especially human fibers such as the hair, comprising the following steps: i) mixing the packaging article as defined above in a composition capable of dissolving the packaging article, ii) applying the resulting composition to the keratinous fibers, iii) allowing to pausing, iv) rinsing said fibers, v) optionally shampooing the fibers, rinsing them and drying them, the composition capable of dissolving the packaging article that may contain an oxidizing agent chemical. Another object of the invention is the use of the packaging article as defined above for dyeing, lightening and / or bleaching the keratinous fibers, preferably the hair. The use of the packaging article makes it possible to obtain consistency compositions which are pleasant to use, easy to mix and to apply and which do not flow outside the zones to be treated.
[0006] When used in a dyeing process, the article makes it possible to obtain coloration having excellent dyeing properties, especially in terms of chromaticity, selectivity, intensity or remanence, which are comparable to or better than those of the compositions of the compositions. conventional packagings ie in separate liquid form and / or good lightening properties of keratin fibers.
[0007] When used in a bleaching process, it provides a good intensity and homogeneity of the discoloration. In addition, the packaging article of the invention makes it possible to have no direct contact between the user and the powdered ingredients. In addition, the packaging article has a size reduced to a bare minimum, very compact, without bulky packaging. According to one embodiment, the article makes it possible to avoid the use of separate bleaching, oxidizing and alkaline compositions and to reduce the number of steps in the staining and / or bleaching process. Other characteristics and advantages of the invention will emerge more clearly on reading the description and examples which follow. In what follows, and unless otherwise indicated, the boundaries of a domain of values are included in this field. The expression "at least one" is equivalent to the expression "one or more". A composition is called "anhydrous" when it comprises a water content of at most 3% by weight, preferably at most 1% by weight relative to the weight of the composition. Preferably, this water content is at most 0.5% by weight relative to the weight of the anhydrous composition. More particularly, the water content varies from 0 to 1% by weight and preferably from 0 to 0.5% by weight relative to the total weight of the composition. By the term "anhydrous paste" is meant an anhydrous composition having a viscosity greater than 5 poise and preferably greater than 10 poise, measured at 25 ° C. and at a shear rate of 1 s -1; this viscosity can be determined by means of a plane Cone rheometer. By the expression in the form of "anhydrous powder" is meant an anhydrous composition or ingredient and in pulverulent form, preferably substantially free of dust (or fine particles). In other words, the particle size distribution is such that the weight ratio of the particles which have a size of less than or equal to 100 micrometers (fines ratio), preferably less than or equal to 65 micrometers (fines ratio), is advantageously less than or equal to 5%, preferably less than 2% and more particularly less than 1% (size of the particles evaluated by means of a RETSCH AS 200 DIGIT granulometer, oscillation height: 1.25 mm / sieving time: 5 minutes). Advantageously, the size of the particles is between 100 μm and 3 mm, more particularly between 65 μm and 2 mm. According to a preferred embodiment of the invention, the anhydrous oxidizing composition is in the form of paste or powder and is introduced into the cavity formed by the envelope. The envelope may consist of a sheet consisting of water-soluble and / or fat-soluble fibers and which is folded on itself or the envelope may be constituted by a first sheet which is covered by a second sheet also made of water-soluble fibers. and / or liposoluble, then the ply folded on itself or the two plies are then assembled (s) hermetically so that the pasta or powders can not diffuse outside, the pasta or powders thus found wrapped by the envelope i) hermetically. By "water-soluble" is meant soluble in water, in particular at least 10 grams per liter of water, preferably at least 20 g / l, more preferably minus 50 g / I, at a temperature of less than or equal to 35 ° C.
[0008] By "liposoluble" is meant soluble in a liquid fatty substance as defined for the ingredient vi) below, in particular in a proportion of at least 10 grams per liter of liquid fatty substance, in particular in a vegetable or mineral oil such as Vaseline oil, preferably at least 20 g / l, a liquid fatty substance, better still at least 50 g / l in a fatty substance, at a temperature of less than or equal to 35 ° C. The term "temperature less than or equal to 35 ° C" means a temperature not exceeding 35 ° C and preferably greater than or equal to 0 ° C, for example ranging from more than 1.0 ° C to 35 ° C, better from 5 ° C to 30 ° C and more preferably from 10 ° C to 30 ° C or 10 ° C to 20 ° C. It is understood that all temperatures are given at atmospheric pressure. The packaging article according to the invention is preferably water-soluble at a temperature of less than or equal to 35 ° C. i) an envelope comprising water-soluble and / or fat-soluble fibers The packaging article according to the invention comprises an envelope which defines at least one cavity, the cavity or cavities containing at least one oxidation oxidizing composition, the packaging article optionally containing at least one alkaline agent in one of its cavities. The packaging article preferably comprises a single cavity. The shell of the present invention comprises one or more water-soluble and / or fat-soluble fiber webs and one or more cavities containing the anhydrous oxidizing composition, the oxidizing composition being distinct from the web or the shell. Such an envelope is different from the water-soluble or liposoluble thin films in which the oxidizing composition would be incorporated into the envelope or sheets forming the envelope. With respect to these water-soluble or fat-soluble thin films, the envelope according to the invention has the advantage of allowing the incorporation of constituents incompatible with this one, to be simpler to implement because it does not require premixing or dissolution in a solvent of the constituents, nor heating to evaporate the solvent. The method of manufacturing the packaging article of the invention is also faster and less expensive than the method of manufacturing thin films.
[0009] In addition, when the active agents, in this case in particular the oxidizing agents, are used in dispersion to form a thin film, this can cause compatibilty problems, mechanical problems (film breakage) and impose active concentration limits. In addition, the envelope and the layers useful for the invention have the advantage of allowing a greater diversity in the choice of the shape and appearance of the article because the water-soluble and / or fat-soluble layer or layers can have a variable thickness and density giving access to a wide variety of shape and size, while the thin film is difficult to dry if the thickness is too great, and it is fragile and difficult to handle if the size is too large .
[0010] Advantageously, the envelope or the plies are "deformable to the touch", that is to say in particular that the envelope and the plies deform when they are gripped and pinched between the fingers of a user. Preferably the anhydrous oxidizing composition in the form of powder or paste is present in a cavity generated by at least two layers constituting the envelope and defining between them a cavity, said sheets preferably comprising water-soluble fibers. According to a particular embodiment of the invention, at least one of the plies of the packaging article consists predominantly, preferably exclusively, of water-soluble fibers, more preferably all the plies of the packaging article of the invention are consisting exclusively of water-soluble fibers, preferably at a temperature of not more than 30 ° C. Preferably, the envelope i) comprises predominantly water-soluble polymer fibers. "Fiber" is understood to mean any object whose length is greater than its section. In other words, it is necessary to understand an object of length L and of diameter D such that L is greater and preferably much higher (ie at least 3 times higher) than D, D being the diameter of the circle in which the fiber cross-section is inscribed, in particular the L / D ratio ( or form factor) is chosen in the range from 3.5 to 2500, preferably from 5 to 500, and more preferably from 5 to 150. The section of a fiber may be of any shape, round, serrated or fluted, or in the form of a bean, but also a multi-lobed, in particular trilobed or pentalobed, X-shaped, ribbon, square, triangular, elliptical, etc. The fibers of the invention may be hollow or not hollow. implemented according to the present invention may be of natural origin, synthetic or artificial. Advantageously, said fibers are of synthetic origin. A "natural fiber" is by definition a fiber naturally present in nature, directly or after mechanical and / or physical treatment. This category includes fibers of animal origin such as cellulose fibers, especially extracted from wood, vegetables or seaweed, rayon. The "artificial fibers" are either totally synthetic or derived from natural fibers which have been subjected to one or more chemical treatments in order to improve in particular the mechanical and / or physicochemical properties.
[0011] "Synthetic fibers" includes fibers obtained by chemical synthesis and are generally fibers consisting of one or more polymers and / or copolymers, mono- or multi-component, composite or otherwise, which are generally extruded and / or stretched to a minimum. to the desired diameter of the fiber.
[0012] Preferably, the fibers of the invention consist of one or more water-soluble polymers. The water-soluble polymer (s) of the invention contain, in their backbones, water-soluble units. The water-soluble units are obtained from one or more water-soluble monomers.
[0013] By "water-soluble monomer" is meant a monomer whose solubility in water is greater than or equal to 1%, preferably greater than or equal to 5% at 25 ° C. and at atmospheric pressure (760 mmHg). The water-soluble synthetic polymer (s) used in the context of the present invention are advantageously obtained from water-soluble monomers comprising at least one double bond. These may be chosen from cationic, anionic and nonionic monomers and mixtures thereof. As water-soluble monomers which can be used as precursors of the water-soluble units, the following monomers which may be in free or salified form, for example: (meth) acrylic acid, - styrenesulfonic acid, vinylsulfonic acid and (meth) allylsulfonic acid, vinylphosphonic acid, N-vinylacetamide and N-methyl-N-vinylacetamide, N-vinylformamide and N-vinylformamide. methyl N-vinylformamide, N-vinyllactams comprising a cyclic alkyl group having from 4 to 9 carbon atoms, such as N-vinylpyrrolidone, N-butyrolactam and N-vinylcaprolactam, maleic anhydride, itaconic acid, - vinyl alcohol of formula CH2 = CHOH, - vinyl ethers of formula CH2 = CHOR in which R is a hydrocarbon radical, linear or branched, saturated or unsaturated, having from 1 to 6 carbons, - halides (chloride ) dimethyldiallyl ammonium, - di methacrylate quaternized methylaminoethyl (MADAME), - (meth) acrylamidopropyltrimethylammonium halides (APTAC and MAPTAC), - methylvinylimidazolium halides (chloride), - 2-vinylpyridine and 4-vinylpyridine, - acrylonitrile, - glycidyl (meth) acrylate, - vinyl halides (vinyl chloride) and vinylidene chloride, - the vinyl monomers of formula (I) below: H 2 C = C (R) -C (O) -X (I) Formula ( I) wherein: - R is selected from H, (C1-C6) alkyl such as methyl, ethyl and propyl; X is chosen from: alkoxy of the type -OR 'where R' is a linear or branched, saturated or unsaturated hydrocarbon radical containing from 1 to 6 carbons, optionally substituted with at least one halogen atom (iodine, bromine, chlorine, fluorine); sulphonic group (-SO3), sulphate (-SO4 phosphate (-PO4H2), hydroxy (-OH), primary amine (-NH2), secondary amine (-NHR6), tertiary (-NR6R7) or quaternary (-N + R6R7R8 ) with R6, R7 and R8 being, independently of one another, a linear or branched, saturated or unsaturated hydrocarbon radical having 1 to 6 carbon atoms, provided that the sum of the carbon atoms of R '+ R6 + R7 + R8 does not exceed 6; -NH2, -NHR 'and -NR'R "groups in which R' and R" are independently of each other linear or branched, saturated hydrocarbon radicals or unsaturated having 1 to 6 carbon atoms, provided that the total number of carbon atoms of R '+ R "does not exceed 6, said R' and R" being optionally substituted with a halogen atom (iodine, bromine, chlorine, fluorine), a hydroxy (-OH) sulphonic (-SO3), sulphate (-SO4), phosphate (-PO4H2), primary amine (-NH2), secondary amine (-NHR6), tertiary (- NR6R7) and / or quaternary (-N + R6R7R8) with R6, R7 and R8 being, independently of one another, a hydrocarbon radical, linear or branched, saturated or unsaturated having 1 to 6 carbon atoms, provided that the sum of the atoms of The compounds of this formula include, for example, N, N-dimethylacrylamide, and N, N-diacylacrylamide. - and their mixtures. As anionic monomers, mention may especially be made of (meth) acrylic acid, acrylamido-2-methylpropanesulfonic acid, itaconic acid and their salts of an alkali metal, alkaline earth metal or ammonium or those derived from an organic amine such as alkanolamine. As nonionic monomers, mention may especially be made of (meth) acrylamide, N-vinylformamide, N-vinylacetoamide and hydroxypropyl (meth) acrylate, vinyl alcohol of formula CH2 = CHOH ,. The cationic monomers are preferably chosen from quaternary ammonium salts derived from a diallylamine, and those corresponding to the following formula (II): ## STR2 ## I) in which: - R1 represents a hydrogen atom or a methyl group, - R2 and R3, identical or different, represent a hydrogen atom or a linear or branched C1-C4 alkyl group, - R4 represents an atom of hydrogen, a linear or branched C1-C4 alkyl group or an aryl group, - D represents the following divalent unit: - (Y), - (A) - in which: - Y represents an amide function, an ester ( 0-C (O) or C (O) -O), a urethane or a urea, A represents a linear or branched, cyclic or acyclic C1-C10 alkylene group which may be substituted or interrupted by a divalent aromatic or heteroaromatic group . The alkylene groups may be interrupted by an oxygen atom, a nitrogen atom, a sulfur atom or a phosphorus atom; the alkylene which can be interrupted by a ketone function, an amide, an ester (O-C (O) or C (O) -O), a urethane, or a urea, n is an integer ranging from 0 to 1; X represents anionic counterion, for example a chloride or a sulphate. As examples of water-soluble cationic monomers, there may be mentioned in particular the following compounds as well as their salts: dimethylaminoethyl (meth) acrylate, (meth) acryloyl-oxyethyltrimethylammonium, (meth) acryloyloxyethyl-dimethylbenzylammonium, N-methyl- [Dimethylaminopropyl] (meth) acrylamide, (meth) acrylamidopropyltrimethylammonium, (meth) acrylamido-propyldimethylbenzylammonium, dimethylaminohydroxypropyl (meth) acrylate, (meth) acryloyloxyhydroxypropyltrimethylammonium, (meth) acryloyloxyhydroxypropyl-dimethylbenzylammonium, and dimethyldiallylammonium. Preferably, the polymer according to the invention is polymerized from at least one cationic monomer as defined above. Preferably, the polymers are polymerized from the monomers comprising at least one double bond: -0 to 30 mol% of acrylic acid, -0 to 95.5 mol% of acrylamide and -0.5 to 100 mol% of at least one cationic monomer represented in formula (II) as defined above.
[0014] Particularly preferred polymers in the invention include those polymerized from -10% acryloyloxyethyldimethylbenzylammonium chloride and 90% acrylamide, -30% acryloyloxytrimethylammonium chloride, 50% sodium chloride, and acryloyloxyethyldimethylbenzylammonium, and 20% acrylamide, -10% acryloyloxyethyltrimethylammonium chloride and 90% acrylamide -30% diallyldimethylammonium chloride and 70% acrylamide -30% acrylic acid and 70% acrylamide. % acrylamide.
[0015] According to a particular embodiment, the polymers are polymerized from a cationic monomer and acrylic acid, the number of moles of the cationic monomer being greater than the number of moles of acrylic acid. As water-soluble polymers derived from natural products, mention may be made of polysaccharides, i.e. polymers with sugar units.
[0016] By "sugar unit" is meant a unit derived from a carbohydrate of formula C n (H 2 O), 4 or (CH 2 O) which may be optionally modified by substitution and / or by oxidation and / or dehydration. The sugar units that may be included in the composition of the polymers of the invention are preferably derived from the following sugars: glucose, galactose, arabinose, rhamnose, mannose, xylose, fucose, fructose, anhydrogalactose, galacturonic acid, glucuronic acid, mannuronic acid , galactose sulfate, anhydrogalactose sulfate. The polymers with a pattern (s) sugar (s) according to the invention can be of natural or synthetic origin. They can be nonionic, anionic, amphoteric or cationic. The base units of the sugar-patterned polymers of the invention may be mono- or disaccharides. Mention may in particular be made, as polymers which may be employed, of the following native gums, as well as their derivatives: a) exudates from trees or shrubs, of which: gum arabic (branched polymer of galactose, arabinose, rhamnose and glucuronic acid); ghatti gum (polymer derived from arabinose, galactose, mannose, xylose and glucuronic acid); karaya gum (polymer derived from galacturonic acid, galactose, rhamnose and glucuronic acid); Tragacanth gum (or tragacanth) (galacturonic acid, galactose, fucose, xylose and arabinose polymer); (b) gums derived from algae, including: - agar (polymer derived from galactose and anhydrogalactose); alginates (polymers of mannuronic acid and glucuronic acid); Carrageenans and furcellerans (polymers of galactose sulfate and anhydrogalactose sulfate); (c) gums derived from seeds or tubers, including: - guar gum (mannose and galactose polymer); carob gum (mannose and galactose polymer); fenugreek gum (mannose and galactose polymer); - tamarind gum (galactose, xylose and glucose polymer); - the konjac gum (glucose polymer and mannose) whose main component is glucomannan is a polysaccharide of high molecular weight (500 000 <Mgluc, omannane <2 000 000) composed of D-mannose units and D- glucose with branching every 50 or 60 units; d) microbial gums including: - xanthan gum (glucose polymer, mannose acetate, mannose / pyruvic acid and glucuronic acid); gellan gum (partially acyl glucose, rhamnose and glucuronic acid polymer); scleroglucan gum (glucose polymer); the gum of biosaccharides (polymer of galacturonic acid, of fucose and of D-galactose) for example that marketed under the name of FUCOGEL 1.5P from SOLABIA (POLYSACCHARIDE RICH IN FUCOSE (20%) AT 1.1% IN WATER STABILIZED (PHENOXYETHANOL 1.5%)), e) plant extracts including: - cellulose (glucose polymer); starch (glucose polymer); Inulin (polymer of fructose and glucose). These polymers can be modified physically or chemically. As a physical treatment, mention may in particular be made of temperature. As chemical treatments, mention may be made of esterification, etherification, amidation and oxidation reactions. These treatments lead to polymers which can be nonionic, anionic, cationic or amphoteric. Preferably these chemical or physical treatments are applied to guar gums, locust bean gums, starches and celluloses. The nonionic guar gums which may be used according to the invention may be modified with hydroxylalkyl groups of 1 to 6 carbon atoms. Among the hydroxyalkyl groups, mention may be made of hydroxymethyl, hydroxyethyl, hydroxypropyl and hydroxybutyl groups. These guar gums are well known in the state of the art and may for example be prepared by reacting corresponding alkene oxides such as, for example, propylene oxides with guar gum, so as to obtain a gum of guar modified with hydroxypropyl groups. The degree of hydroxyalkylation preferably ranges from 0.4 to 1.2 and corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functions present on the guar gum.
[0017] Such nonionic guar gums optionally modified with hydroxyalkyl groups are for example sold under the trade names Jaguar HP8, Jaguar HP60 and Jaguar HP120 by Rhodia Chimie.
[0018] The guar gums modified with cationic groups that are more particularly usable according to the invention are guar gums comprising cationic trialkylammonium groups. Preferably, 2 to 30% by number of the hydroxyl functions of these guar gums carry trialkylammonium cationic groups. Even more preferably, 5 to 20% of the number of hydroxyl functions of these guar gums are connected by cationic trialkylammonium groups. Among these trialkylammonium groups, there may be mentioned very particularly trimethylammonium and triethylammonium groups. Even more preferentially, these groups represent from 5 to 20% by weight relative to the total weight of the modified guar gum.
[0019] According to the invention, it is possible to use guar gums modified with 2,3-epoxypropyltrimethylammonium chloride. These guar gums modified with cationic groups are products already known in themselves and are described, for example, in US Pat. Nos. 3,589,578 and 4,013,307. Such products are also sold in particular under the trade names of Jaguar. C13 S, JAGUAR C 15, JAGUAR C 17 by RHODIA CHEMISTRY. As modified locust bean gum, it is possible to use cationic carob gum containing hydroxypropyltrimmonium groups, such as the Catinal CLB 200 proposed by the company TOHO.
[0020] The starch molecules used in the present invention may originate from all plant sources of starch, including cereals and tubers; more particularly it may be corn starch, rice, cassava, barley, potato, wheat, sorghum, peas, oats, tapioca. It is also possible to use the hydrolysates of the starches mentioned above. The starch is preferably from the potato. The starches may be modified chemically or physically, in particular by one or more of the following reactions: pregelatinization, oxidation, crosslinking, esterification, etherification, amidification, heat treatments. More particularly, these reactions can be carried out as follows: - pregelatinization by bursting the starch granules (for example drying and cooking in a drying drum); oxidation by strong oxidants leading to the introduction of carboxyl groups into the starch molecule and to the depolymerization of the starch molecule (for example by treating an aqueous starch solution with sodium hypochlorite); crosslinking with functional agents capable of reacting with the hydroxyl groups of the starch molecules which will thus be bonded together (for example with glyceryl and / or phosphate groups); alkaline esterification for the grafting of functional groups, in particular C1-C6 acyl (acetyl), hydroxyalkyl C1-C6 (hydroxyethyl, hydroxypropyl), carboxymethyl, octenylsuccinic. In particular, it is possible to obtain, by means of crosslinking with phosphorus compounds, mono-starch phosphates (of the Am-O-PO- (OX) 2 type), diamidon phosphates (of the Am-O-PO- (OX) -O-Am type). or even triamidon (of the type Am-O-PO- (O-Am) 2) or mixtures thereof; with Am signifying starch and X denoting in particular the alkali metals (for example sodium or potassium), the alkaline earth metals (for example calcium, magnesium), the ammonium salts, the amine salts such as those of monoethanolamine, diethanolamine, triethanolamine, 3-aminopropanediol-1,2, ammonium salts derived from basic amino acids such as lysine, arginine, sarcosine, ornithine, citrulline. The phosphorus compounds may be, for example, sodium tripolyphosphate, sodium orthophosphate, phosphorus oxychloride or sodium trimetaphosphate.
[0021] Diamidon phosphates or diamidon phosphate-rich compounds such as the product proposed under the references PREJEL VA-70-T AGGL (hydroxypropylated gelatinized hydroxypropyl diamidon phosphate) or PREJEL TK1 (gelatinized manioc diamidon phosphate) are preferably used. PREJEL 200 (acetylated gelatinized manioc diamidon phosphate) by the company AVEBE or STRUCTURE ZEA by NATIONAL STARCH (gelatinized cornstarch). A preferred starch is a starch which has undergone at least one chemical modification such as at least one esterification. According to the invention, it is also possible to use amphoteric starches comprising one or more anionic groups and one or more cationic groups. The anionic and cationic groups may be bonded to the same reactive site of the starch molecule or to different reactive sites; preferably they are linked to the same reactive site. The anionic groups may be of carboxylic, phosphate or sulfate type, and preferably carboxylic. The cationic groups may be of primary, secondary, tertiary or quaternary amine type.
[0022] The amphoteric starches are chosen in particular from compounds of the following formulas: ## STR2 ## ## STR2 ## ## STR2 ## ) R 'R (IV) COOM H HC - C - COOM R' R "R", St - O - C - C - COOM St - O - C - C - COOM H2 HH H2 Formulas (III) to (VI) in which: - St-0 represents a starch molecule; - R, identical or different, represents a hydrogen atom or a methyl radical; - R ', identical or different, represents a hydrogen atom, a methyl radical; or a group -O (O) -OH; n is an integer equal to 2 or 3; M, identical or different, denotes a hydrogen atom, an alkali metal or alkaline earth metal such as Na, K, Li, a quaternary ammonium NH4, or an organic amine; R "represents a hydrogen atom or a C1-C18 alkyl radical; These compounds are in particular described in US5455340 and US4017460. Starches of formula (IV) or (V) are particularly used; and preferably starches modified with 2-chloroethylaminodipropionic acid, that is to say starches of formula (IV) or (V) in which R, R ', R "and M represent a hydrogen atom and n is 2. The preferred amphoteric starch is a starch chloroethylamido dipropionate The celluloses and cellulosic derivatives may be anionic, cationic, amphoteric or nonionic.
[0023] Among these derivatives, there are cellulose ethers, cellulose esters and cellulose ether esters. Among the cellulose esters, mention may be made of inorganic esters of cellulose (cellulose nitrates, sulphates or phosphates), organic cellulose esters (cellulose monoacetates, triacetates, amidopropionates, acetatebutyrates, acetatepropionates or acetatetrimellitates) and mixed organic esters. inorganic cellulose such as acetate-butyrate sulphates and cellulose acetate propionates. Among the cellulose ether esters, mention may be made of hydroxypropyl methylcellulose phthalates and ethylcellulose sulphates.
[0024] Among the nonionic cellulose ethers, mention may be made of alkylcelluloses such as methylcelluloses and ethylcelluloses (for example Ethocel Standard 100 Premium from DOW CHEMICAL); hydroxyalkylcelluloses such as hydroxymethylcelluloses, hydroxyethylcelluloses (for example Natrosol 250 HHR proposed by AQUALON) and hydroxypropylcelluloses (for example Klucel EF from AQUALON); mixed hydroxyalkyl-alkylcellulose celluloses such as hydroxypropyl-methylcelluloses (for example Methocel E4M from Dow Chemical), hydroxyethyl-methylcelluloses, hydroxyethylethylcelluloses (for example Bermocoll E 481 FQ from Akzo Nobel) and hydroxybutyl-methylcelluloses.
[0025] Among the anionic cellulose ethers, mention may be made of carboxyalkylcelluloses and their salts. As an example, there may be mentioned carboxymethylcelluloses, carboxymethylmethylcelluloses (for example Blanose 7M from AQUALON) and carboxymethylhydroxyethylcelluloses, as well as their sodium salts. Among the cationic cellulose ethers, mention may be made of quaternized hydroxyethylcelluloses which may or may not be crosslinked. The quaternizing agent may especially be diallyldimethylammonium chloride (for example Celquat L200 from National Starch). Another cationic cellulose ether which may be mentioned is hydroxyethyl cellulose hydroxypropyltrimethylammonium (for example Ucare polymer JR 400 from AMERCHOL). Among the associative polymers with a sugar unit (s), mention may be made of celluloses or their derivatives, modified with groups comprising at least one fatty chain, such as alkyl, arylalkyl or alkylaryl groups, or mixtures thereof, where the alkyl groups are C8-C22; nonionic alkylhydroxyethylcelluloses such as the products NATROSOL PLUS GRADE 330 CS and POLYSURF 67 (C16 alkyl) sold by AQUALON; quaternized (cationic) alkylhydroxyethylcelluloses such as the products QUATRISOFT LM 200, QUATRISOFT LM-X 529-18-A, QUATRISOFT LM-X 529-18-B (C12 alkyl) and QUATRISOFT LM-X 529-8 (C18 alkyl) ) sold by the company Amerchol, the products CRODACEL QM, CRODACEL QL (C12 alkyl) and CRODACEL QS (C18 alkyl) sold by the company CRODA and the product SOFTCAT SL 100 sold by the company AMERCHOL; nonionic nonoxynylhydroxyethylcelluloses such as the AMERCELL HM-1500 product sold by the company Amerchol; nonionic alkylcelluloses such as the BERMOCOLL EHM 100 product sold by the company BEROL NOBEL. As polymers having sugar (s) derived from associative guar, mention may be made of hydroxypropyl guars modified with a fatty chain such as the product ESAFLOR HM 22 (modified with a C22 alkyl chain) sold by the company LAMBERTI; the product MIRACARE XC 95-3 (modified with a C14 alkyl chain) and the product RE 205-146 (modified with a C20 alkyl chain) sold by RHODIA CHIMIE. The sugar-based polymer (s) of the invention are preferably chosen from guar gums, locust bean gums, xanthan gums, starches and celluloses, in their modified form (derivatives). or not modified. Preferably, the polymers with a sugar unit (s) according to the invention are nonionic. More preferably, the polymer (s) sugar (s) of the invention are chosen from modified nonionic guar gums, in particular modified by hydroxyalkyl groups C 1 -C 6. The polymers described above more particularly have a molecular weight greater than 1,000,000 and preferably between 1,000,000 and 50,000,000. The molecular weight is determined by the method RSV (Reduced Specific Viscocity) as defined in " Principles of Polymer Chemistry "Cornell University Press, Ithaca, NY 1953 Chapter VII" Determination of Molecular Weight "pp. 266-316. The fibers can be spun, carded or twisted. Advantageously, the fibers used in the context of the present invention are spun. The average diameter of the fibers used according to the present invention, which is identical or different, is less than 500 μm. Advantageously, such a diameter is less than 200 μm, preferably less than 100 μm, or even less than 50 μm. Water-soluble fibers that include polyvinyl alcohol-based fibers (PVA), polysaccharide fibers such as glucomannans, starches, celluloses, such as carboxymethylcelluloses, polyalginic acid fibers, polylactic acid, and the polyalkylene oxide fibers, as well as their mixture. More preferentially, the water-soluble fiber or fibers used in the invention are chosen from PVA-based fibers. The fibers of the envelope or webs are generally entangled. As indicated above, the term "envelope or sheet comprising water-soluble fibers" means an envelope or sheets which may consist entirely of water-soluble fibers or a sheet which may comprise both soluble fibers in the form of water-soluble fibers. water and insoluble fibers in water at a temperature of 35 ° C or lower, the soluble fibers to be in greater quantity than the insoluble fibers. The fiber web must comprise at least 60% by weight of soluble fibers, preferably at least 70% and better still at least 80% by weight relative to the total weight of the fibers.
[0026] It can thus comprise, for example, more than 95% by weight, or even more than 99% by weight and even 100% by weight of water-soluble fibers relative to the total weight of the fibers of the envelope or webs. When the fiber web contains insoluble fibers, these may be of any material usually used as insoluble fiber; it can be for example silk fibers, cotton, wool, linen, polyamide (Nylon®), polylactic acid, modified cellulose (rayon, viscose, rayon acetate), poly-p phenylene terephthalamide, in particular Kevlar®, polyolefin and especially polyethylene or polypropylene, glass, silica, aramid, carbon in particular in graphite form, Teflon®, insoluble collagen, polyesters, polyvinyl chloride or vinylidene, polyethylene terephthalate, fibers formed from a mixture of the above-mentioned compounds, such as polyamide / polyester or viscose / polyester fibers. In addition, the envelope and the webs of the invention may be woven or non-woven.
[0027] According to a particular embodiment, the envelope and the webs of the invention are woven. In the context of the present invention, a "woven" material results from an organized assembly of fibers, in particular of water-soluble polymeric fibers, and more particularly of an intersection, in the same plane, of said fibers, arranged in the direction of the warp and fibers arranged, perpendicular to the warp fibers, in the weft direction. The binding obtained between these warp and weft fibers is defined by an armor. Such a woven material results from an operation to assemble the fibers in an organized manner such as weaving itself, but may also result from knitting.
[0028] More particularly, the two layers or webs comprising the woven polymeric water-soluble fibers which constitute the envelope of the packaging article of the invention do not include any additional layer superimposed on them. According to another particularly advantageous embodiment of the invention, the envelope and the plies are non-woven. Nonwovens are generally described in RIEDEL "Nonwoven Bonding Methods & Materials", Nonwoven World (1987), incorporated herein by reference. For the purposes of the present invention, the term "nonwoven" means a substrate comprising fibers, in particular of water-soluble polymeric fibers, in which the individual fibers are arranged in a disordered manner in a sheet-like structure and which are not woven, neither knitted. The fibers of the nonwoven are generally bonded together, either under the effect of a mechanical action (eg needling, air jet, water jet, etc.), or under the effect of a thermal action , or by adding a binder.
[0029] Such a nonwoven is for example defined by the ISO 9092 standard as a web or a layer of directionally or randomly oriented fibers, linked by friction and / or cohesion and / or adhesion, excluding paper and products obtained by weaving, knitting, tufting or stitching incorporating binding yarns or filaments. A nonwoven differs from a paper by the length of the fibers used. In paper, the fibers are shorter. However, there are nonwovens based on cellulosic fiber which are made wet and have short fibers as in paper. The difference between a nonwoven and a paper is generally the absence of hydrogen bonding between the fibers in a nonwoven.
[0030] Very preferably, the fibers used in the context of the present invention are chosen from synthetic fibers such as PVA fibers. Particularly the envelope and webs of the invention are nonwoven, and preferably non-woven PVA fibers.
[0031] In order to produce the water-soluble web (s), preferably non-woven fabrics, of the envelope of the packaging article, water-soluble PVA fibers at a temperature of less than or equal to 35 ° C are preferably used, such as for example, the fibers sold by the Japanese company Kuraray under the name Kuralon KI I, and particularly the soluble WN2 grade from 20 ° C. These fibers are described in EP-A-636716 which teaches the manufacture of water-soluble PVA fibers at temperatures not exceeding 100 ° C., by spinning and stretching the polyvinyl alcohol polymer in the dry state. or wet in the presence of solvents involved in the solubilization and solidification of the fiber. The fiber thus obtained can lead to the production of woven or non-woven substrates. According to one particular embodiment of the invention, the PVA fibers of the examples of EP-A-636716 are used, in particular Example 2 and Comparative 1: SOLVRON SS commercial product. These fibers can also be prepared from a solution by spinning, dissolving a water-soluble PVA-based polymer in a first organic solvent, spinning the solution into a second organic solvent to obtain solidified filaments, and wet stretching the filaments from which the first solvent and then dried and subjected to heat treatment. The section of these fibers may be substantially circular. These fibers have a tensile strength of at least 2.7 g / dtex (3 g / d). EP-A-0 636 716 describes such water-soluble PVA-based fibers and their method of manufacture. For example, the fibers can also be formed by extrusion and deposited on a conveyor to form a sheet of fibers which is then consolidated by a conventional technique of fiber bonding, such as, for example, needling, hot-bonding, calendering or the linking by jets of hot air (in English air through bonding), technique in which the water-soluble sheet passes through a tunnel where is blown hot air, or hydrolysis to bind the fibers under the action of fine jets of water under very high pressure, which can not be applied to fibers whose dissolution temperature is too low pressure. As we have seen previously, the invention is not limited to the use of PVA, and it is also possible to use fibers made of other water-soluble materials provided that these materials dissolve in water having the desired temperature, for example polysaccharide fibers marketed under the name LYSORB by the company LYSAC TECHNOLOGIES, INC or other polysaccharide-based polymer fibers such as glucomannans or starches. The layers of the envelope may comprise a mixture of different fibers soluble in water at different temperatures (up to 35 ° C). The fibers may be composite, and they may comprise for example a core and a sheath of the same nature, for example formed of different grades of PVA.
[0032] According to a particular embodiment of the invention, the layer or plies of the envelope are a nonwoven, comprising water-soluble fibers, alone or mixed with insoluble fibers as indicated above, with at most 40% by weight. insoluble fiber weight relative to the total weight of the fibers constituting the web. Preferably, the nonwoven consists essentially of water-soluble fibers, i.e. it does not contain insoluble fibers. The envelope may have any shape suitable for the intended use, for example a rectangular, round or oval shape, and it preferably has dimensions allowing its gripping between two fingers at least. Thus, the envelope or the layers may have for example an ovoid shape of about 2 to 10 cm long and about 0.5 to 4 cm wide, or a circular disc shape of about 2 to 10 cm of diameter, or a square shape of about 5 to 15 cm square, or a rectangle shape of a length of about 5 to 25 cm, it being understood that it may have any other shape and size suitable for sought-after use. Advantageously, the envelope and the layers have a small thickness, the layers may consist of several layers. Preferably the thickness of the envelope and webs ranges from 3% to 99.9% of its other dimensions. This thickness is in particular less than 100 mm. The envelope and the layers are thus substantially flat, thin slices. The surface delimiting the cavity or cavities has an extent generally less than 625 cm 2, and for example between 400 cm 2 and 0.025 cm 2. One can for example use an envelope and webs as defined in the French patent application FR 12 611 20 filed November 22, 2012 by the Applicant. The article according to the present invention may comprise one or more water-soluble nonwoven webs and envelopes. Preferably, the amount of the envelope present in the article according to the invention is between 0.5% and 20.0% by weight, based on the total weight of said article; advantageously included inclusively between 1.0% and 10.0%, especially between 2.0% and 5.0% inclusive; more particularly 3% by weight relative to the total weight of the packaging article. Figure la) represents a cross-section of a particular embodiment of the packaging article comprising the envelope i) consisting of two sheets, preferably water-soluble, 11 and 12 joined together at a peripheral region 14 Preferably, the two plies are joined by any suitable fastening means such as gluing, welding especially heat sealing, in particular by entanglement. The first ply 11 furthermore has a free central region D arranged opposite a free central region D of the second ply 12. These two central regions delimit a central cavity, said cavity contains an anhydrous oxidizing composition as defined above. comprising at least one anhydrous oxidizing agent optionally mixed with other powdered ingredients. The plies 11 and 12 have a closed outer periphery. The shape of the outer periphery 15 is for example rounded, such as circular or elliptical, or polygonal, such as square, rectangular, triangular, preferably circular. Figure 1 b) shows a view from above of the packaging article as described in FIG. 1 a) in which part D corresponds to the cavity or "central region" in which the anhydrous discoloration composition 13 is located and d corresponds to the peripheral region which joins the two sheets 11 and 12 hermetically. FIG. 1c) represents a cross-section of a particular embodiment of the packaging article comprising an envelope consisting of two sheets 11 and 12 that are preferably water-soluble, and comprising an additional layer 16, preferably water-soluble, and possibly other layers. additional layers 17 preferably water-soluble, which define several cavities in which are housed the ingredients such as the anhydrous oxidizing composition as defined above comprising at least one anhydrous oxidizing agent 18 as defined below, and optionally at least one alkaline agent 19 as defined below,. The first ply 11 has a thickness less than its other dimensions, for example less than 10% of its maximum transverse dimension D + 2d. The thickness of the first ply 11 is for example less than 10 mm and in particular between 0.1 mm and 3 mm. Its maximum transverse dimension D + d is for example less than 100 mm, and is in particular between 10 mm and 60 mm inclusive.
[0033] The first ply 11 thus forms a layer, for example of non-woven fabric itself, which may consist of several layers of non-woven fabrics bound together. The second ply 12 also has a closed outer periphery. The outer periphery 15 of the first layer 11 is substantially identical in shape to the outer periphery 15 of the second layer 12.
[0034] The second, preferably water-soluble, ply 12 has a thickness less than its other dimensions, for example less than 10% of its maximum transverse dimension D + 2d. The thickness of the second sheet 12 preferably water-soluble is for example less than 10 mm and in particular between 0.1 mm and 3 mm. Its maximum transverse dimension D + 2d is less than 100 mm, and is in particular between 10 mm and 60 mm. The thickness is advantageously measured according to the EDANA WSP 120.1 (5) standard. The second ply 12 is advantageously a nonwoven.
[0035] The first ply 11 and the second ply 12, which may be identical or of different thicknesses, densities and / or compositions, are preferably water-soluble nonwovens at a temperature of less than or equal to 35 ° C. The nonwoven webs and wrap are soluble in an aqueous solution, such as water. The envelope and nonwoven webs are preferably in PVA.
[0036] As a variant, the second ply may be formed by the first folded ply on itself 11 'represented by FIG. 1d) in cross-section and FIG. 1 e) with a view from above. The ply is folded on itself along the fold axis e which defines a cavity in which the oxidizing composition as defined above and below comprising at least anhydrous chemical oxidizing agent 18 'as defined below, is located, and optionally at least one alkaline agent as defined hereinafter preferably in powder form and / or excipients as defined below, preferably in powder 19 'optionally separated by one or more water-soluble plies 16'. The web 11 'once filled with the ingredients 19' and the water-soluble ply or plies 16 ', is folded along the axis e, forming a fold zone 15' and then joined at a peripheral region 14, hatched portion of fig. e), preferably by any suitable fastening means such as gluing, welding including heat sealing, in particular by entanglement. The thickness of the water-soluble sheet 11 'and the transverse dimensions correspond to the same criteria as those defined for the sheet 11 or 12 of FIG. 1 b).
[0037] The fibers forming the first ply 11, or 11 'and the second ply 12, and the additional plies 16, 16', and 17 are preferably water-soluble, i.e. made of water-soluble fibers. These fibers are, for example, non-woven water-soluble fibers, such as PVA fibers, polysaccharide fibers such as glucomannans or starches, or any other polymer or compound capable of forming fibers or yarns, obtained for example by extrusion, soluble in water. The plies 11, 11 'and 12 and the additional optional plies 16, 16' and 17, preferably of non-woven generally have a grammage less than or equal to 60 g / m2, or even less than or equal to 50 g / m2, even better less than or equal to 45 g / m2. Alternatively, the basis weight of at least one layer may be greater than 60 g / m 2.
[0038] The packaging articles comprising water-soluble fibers according to the invention are preferably soluble in water or in an aqueous composition with a dissolution time of the packaging article which is preferably at most one hour.
[0039] Process for preparing the packaging article: The envelope i) delimits or defines a cavity which is filled with an anhydrous oxidizing composition as defined above ii) preferably in powder or paste comprising at least one anhydrous chemical oxidizing agent such as defined below, and optionally at least one alkaline agent, preferably in powder or paste, the article is then closed by folding the envelope i) as defined above on itself with its content followed by an assembly at its periphery, for example by gluing or welding, preferably by heat-sealing, or if the article contains an envelope constituted by two plies, is deposited on the first ply an anhydrous oxidizing composition ii) preferably in powder or paste, the article is closed with a second ply that covers the ingredients ii) deposited on the first ply and which is assembled for example by gluing or welding to s peripherally, preferably by heat sealing at its periphery, so as to obtain a sealed article, which does not pass through the atmosphere powders or pasta contained in said article. When the envelope and the plies comprise several water-soluble sheets of non-woven fabrics, these can be assembled in particular by heat-sealing at their periphery. Preferably the heat sealing is performed with entanglement of the fibers of the parts of the envelope to be welded. ii) Chemical Oxidizing Agent As previously indicated, the anhydrous oxidizing composition comprising at least one anhydrous chemical oxidizing agent which may be in the form of paste or powder, preferably in the form of a powder. By chemical oxidizing agent is meant an oxidizing agent different from the oxygen of the air. The anhydrous chemical oxidizing agent may be chosen from peroxygenated salts such as, for example, persulfates, perborates, peracids and their precursors, alkali metal or alkaline-earth metal percarbonates, such as sodium carbonate peroxide or sodium percarbonate. ; alkali metal bromates or ferricyanides, solid hydrogen peroxide-generating oxidizing agents such as urea peroxide and polymeric complexes capable of releasing hydrogen peroxide, especially those comprising a vinyl heterocyclic monomer such as polyvinylpyrrolidone complexes; H202 in particular being in the form of powders; oxidases producing hydrogen peroxide in the presence of a suitable substrate (for example glucose in the case of glucose oxidase or uric acid with uricase), and mixtures thereof. Preferably, the persulfate (s) are chosen from persulfates of sodium, potassium and ammonium, and mixtures thereof.
[0040] With regard to the complexes of hydrogen peroxide and polymer containing as monomer at least one vinyl heterocyclic monomer, the vinyl heterocyclic monomer may be chosen from monomers comprising a heterocycle having 4 to 6 ring members, optionally fused to a ring benzene and comprises from 1 to 4 identical or different intracyclic heteroatoms; the number of intracyclic heteroatoms being lower than that of the heterocyclic rings. Preferably, the number of intracyclic hetero atoms is 1 or 2. More particularly, the heteroatom (s) are chosen from sulfur, oxygen and nitrogen, preferably from nitrogen and oxygen. According to an even more advantageous embodiment of the invention, the monomer comprises at least one intracyclic nitrogen atom. The vinyl heterocycle may optionally be substituted by one or more C1-C4 alkyl groups, preferably C1-C2 alkyl groups. Preferably, the heterocyclic monomer is selected from N-vinyl monomers.
[0041] Among the monomers that can be envisaged, there may be mentioned the following optionally substituted monomers: N-vinylpyrrolidone, vinylcaprolactam, Nvinylpiperidone, N-vinyl-3-morpholine, N-vinyl-4-oxazolinone, 2-vinylpyridine, 4- vinylpyridine, 2-vinylquinoline, 1-vinylimidazole, 1-vinylcarbazole. Preferably, the monomer is optionally substituted N-vinylpyrrolidine.
[0042] According to a particularly advantageous embodiment of the invention, the polymer is a homopolymer. However, it is not excluded to use a copolymer. In such a case, the comonomer or comonomers are chosen from vinyl acetate, (meth) acrylic acids, (meth) acrylic amides, substituted (meth) acrylic acid C1-C4 alkyl esters or no. The polymer involved in this complex may moreover be soluble or insoluble in water. Preferably, it is soluble in water. It can have variable average molecular weights, preferably between 103 and 3.106 g / mol, preferably between 103 and 2.106 g / mol. It is also possible to use mixtures of such polymers.
[0043] Advantageously, said complex comprises from 10 to 30% by weight of hydrogen peroxide, more particularly from 13 to 25% by weight and preferably from 18 to 22% by weight, relative to the total weight of the complex. According to a still more advantageous variant of the invention, in this complex, the molar ratio between the vinyl heterocyclic monomer (s) and the hydrogen peroxide ranges from 0.5 to 2, preferably from 0.5 to 1. This complex is advantageously in the form of a substantially anhydrous powder, that is to say containing less than 5% by weight of water. Complexes of this type are described in particular in US5,008,106, US5,077,047, EP 832846, EP 714919, DE 4344131, DE 19545380 and the other polymeric complexes described in US 5,008,093; US 3,376,110; US 5,183,901. By way of examples of complexes, mention may be made, for example, of the products of the Peroxydone K-30, Peroxydone K-90, Peroxydone XL-10 type as well as the complexes formed with hydrogen peroxide and one of the following polymers of Plasdone K-17, Plasdone K-25, Plasdone K-29/32, Plasdone K-90, Polyplasdone INF-10, Polyplasdone XL-10, Polyplasdone XL, Plasdone S-630, Styleze 2000 Terpolymer, Ganex copolymer series, marketed by ISP. Preferably, the chemical oxidizing agent is chosen from peroxygenated salts, preferably from persulfates, alkali metal or alkaline earth metal percarbonates, such as sodium carbonate peroxide or sodium percarbonate, the polymeric complexes being able to liberate hydrogen peroxide, especially those comprising a vinyl heterocyclic monomer such as polyvinylpyrrolidone / H 2 O 2 complexes and mixtures thereof.
[0044] More preferably, the chemical oxidizing agent selected from alkali metal or alkaline earth metal percarbonates such as sodium percarbonate. The concentration of anhydrous chemical oxidizing agents in the oxidizing composition according to the invention varies generally from 10 to 97% by weight, preferably from 30 to 90% by weight, better still from 50 to 85% by weight, more preferably from 60 to 85% by weight. at 85% of the total weight of the oxidizing composition. Other ingredients The packaging article according to the invention may comprise other ingredients.
[0045] The packaging article may in particular contain iii) one or more alkaline agents.
[0046] The alkaline agent (s) may be in the packaging article associated with the anhydrous chemical oxidizing agents ii), or may be separated from the oxidizing agents by one or more layers as defined above. The alkaline agent (s) may, for example, be chosen from inorganic alkaline agents such as ammonium or tribasic ammonium phosphate, water-soluble silicates such as alkali metal or alkaline-earth metal silicates, such as sodium disilicate and metasilicate. sodium, phosphates or carbonates of alkali or alkaline earth metals, such as lithium, sodium, potassium, magnesium, calcium, barium, and mixtures thereof and organic alkaline agents such as alkanolamines. Preferably, the alkaline agent (s) are inorganic and preferably chosen from water-soluble silicates such as alkali or alkaline-earth metal silicates, alkali metal or alkaline-earth metal carbonates, and mixtures thereof. In the context of the invention, the term "water-soluble silicate" means a silicate which has a solubility in water at 25 ° C. of greater than 0.5%, preferably greater than 1% by weight. These water-soluble silicates differ from aluminum silicates and their derivatives, especially clays, such as mixed silicates of natural or synthetic origin which are insoluble in water.
[0047] The concentration of alkaline agents is generally between 0.1 and 40% by weight, and preferably between 0.5 and 30% by weight, and better still between 1 and 25% by weight of the total weight of the oxidizing composition or of the composition. conditioning agent. According to a particular embodiment of the invention, the packaging article contains iv) one or more ammonium salts. The ammonium salt or salts that may be in the packaging article are either associated with the oxidizing agents or are separated from the oxidizing agents by one or more water-soluble or liposoluble layers as defined above, defining a cavity in which is housed the said salt or salts.
[0048] According to a particular variant, the packaging article comprises one or more ammonium salts chosen from ammonium halides, such as ammonium chloride, ammonium sulfate, ammonium phosphate or ammonium nitrate. . According to an even more advantageous embodiment of the invention, the ammonium salt is ammonium chloride or ammonium sulfate.
[0049] The concentration of ammonium salt (s), if they are present, is advantageously between 0.01% and 40% by weight relative to the total weight of the composition (s) contained in the packaging article, preferably from 0.1 to 30% by weight relative to the total weight of the composition or compositions contained in the packaging article. In the case where it is in the form of a paste, the oxidizing composition according to the invention may further comprise v) one or more liquid fatty substances. For the purpose of the present invention, the term "liquid fatty substance" means any fatty substance capable of flow at ambient temperature, generally between 15 ° C. and 40 ° C., and at atmospheric pressure, under the action of its own weight. As examples of liquid fatty substances, mention may be made of polydecenes of formula C1onH [(2oa) +2] in which n varies from 3 to 9 and preferably from 3 to 7, the esters and in particular the esters of fatty alcohols or fatty acids, esters or diesters of C12-024 fatty acid sugars, or cyclic esters, cyclic ethers, silicone oils, mineral oils, vegetable oils or animal oils , or their mixtures. Preferably, the liquid fatty substance or fats are chosen from polydecenes of formula C1on1-1 [(20n) +2] in which n varies from 3 to 9 and preferably from 3 to 7, the esters of fatty alcohols or of fatty acids, petrolatum or paraffin oils, and mixtures thereof.
[0050] Preferably, one or more mineral oil (s) can be found in the packaging article, in particular associated with the anhydrous chemical oxidizing agent (s), such as, for example, paraffin oil, petroleum jelly, preferably petroleum jelly. The content of liquid fatty body (s) varies, in the composition (s) contained in the packaging article, if it (they) is (are) present (s) advantageously from 10 to 50% by weight per relative to the weight of the composition (s) contained in the packaging article, and preferably from 20 to 50% by weight relative to the weight of the composition (s) contained in the packaging article.
[0051] The anhydrous composition according to the invention in the form of a paste and comprising a liquid fatty substance can be advantageously prepared by dispersing, under mechanical action, all the compounds in the form of powder in the liquid fatty substance, in which one has previously dispersed or mixed the other liquid compounds of the composition.
[0052] The dough can also be prepared by extrusion, by introducing the liquid and solid phases of the composition into an extruder, and then mixing them at a temperature below 25 ° C using a co-rotating twin-screw compound system. of transport and kneading elements.
[0053] According to a particular embodiment, the packaging article of the invention comprises (vi) one or more thickening polymer (s). The latter (s) that may be in said article with the chemical oxidizing agent (s) anhydrous (s) is separated (s) from the other ingredients by one or more tablecl (s) water soluble (s) as defined previously. Advantageously, the thickening polymers are chosen from the following polymers: (a) nonionic amphiphilic polymers comprising at least one fatty chain and at least one hydrophilic unit; (b) anionic amphiphilic polymers having at least one hydrophilic unit, and at least one fatty chain unit; (c) crosslinked acrylic acid homopolymers; (d) cross-linked homopolymers of 2-acrylamido-2-methyl-propane sulfonic acid and their partially or fully neutralized acrylamide cross-linked copolymers; (e) homopolymers of ammonium acrylate or copolymers of ammonium acrylate and acrylamide; (f) homopolymers of dimethylaminoethyl methacrylate quaternized with methyl chloride or copolymers of dimethylaminoethyl methacrylate quaternized with methyl chloride and acrylamide; (g) polysaccharides such as: (g1) scleroglucan gums (biopolysaccharide of microbial origin), (g2) gums derived from plant exudates such as gum arabic, Ghatti, Karaya and Tragacanthe; and (g3) celluloses and derivatives; (g4) guar gums and derivatives; or (g5) starches or derivatives It should be noted that in the case of the present invention, the thickening polymers have a role on the viscosity of the ready-to-use composition, that is to say of the resulting composition mixing the packaging article according to the invention with an aqueous composition.
[0054] According to the invention, the amphiphilic polymers are more particularly hydrophilic polymers capable, in the medium of the composition, and more particularly an aqueous medium, of reversibly associating with each other or with other molecules. Their chemical structure more particularly comprises at least one hydrophilic zone and at least one hydrophobic zone. Hydrophobic group is understood to mean a radical or polymer with a hydrocarbon chain, saturated or unsaturated, linear or branched, comprising at least 8, preferably at least 10 carbon atoms, preferably from 10 to 30 carbon atoms, in particular from 12 to to 30 carbon atoms and more preferably from 18 to 30 carbon atoms. Preferably, the hydrocarbon group comes from a monofunctional compound. By way of example, the hydrophobic group may be derived from a fatty alcohol such as stearyl alcohol, dodecyl alcohol or decyl alcohol. It can also denote a hydrocarbon polymer such as for example polybutadiene. The thickening polymers are preferably used in an amount ranging from 0.01 to 15% by weight relative to the weight of the composition or compositions contained in the packaging article, and preferably from 0.1 to 10% by weight. relative to the weight of the composition or compositions contained in the packaging article. According to a particular embodiment, the packaging article of the invention comprises vii) one or more surfactants. The latter may be in said article either with the oxidizing agent (s) or separated from the other ingredients by one or more water-soluble layers as defined above, which define a cavity in which is housed the one or more surfactants. Preferably vii) are with the oxidizing agent (s) in the packaging article.
[0055] For the purpose of the present invention, the term "surfactant" is intended to mean an agent comprising at least one hydrophilic group and at least one lipophilic group in its structure, and which is preferably capable of reducing the surface tension of the water, and comprising in its structure, as possible repeating units, alkylene oxide units and / or sugar units and / or siloxane units. Preferably, the lipophilic group is a fatty chain comprising from 8 to 30 carbon atoms. This or these surfactants may be chosen from anionic, amphoteric, nonionic or cationic surfactants or mixtures thereof. More particularly, the surfactants are chosen from nonionic and anionic surfactants.
[0056] The surfactants that are suitable for the implementation of the present invention are in particular the following: (a) Anionic surfactant (s): The term "anionic surfactant" means a surfactant comprising as ionic or ionizable groups only anionic groups. These anionic groups are preferably chosen from the groups -C (O) OH, -C (O) O-, -503H, -S (O) 20-, -OS (O) 20H, -OS (O) 20- , -P (O) OH 2, -P (O) 20 -, - P (O) O 2, -P (OH) 2, = P (O) OH, -P (OH) O-, = P (O) 0-, = POH, = PO-, the anionic parts comprising a cationic counter ion such as those derived from an alkali metal, an alkaline earth metal, or an amine or an ammonium.
[0057] As examples of anionic surfactants that may be used in the composition according to the invention, mention may be made of alkyl sulphates, alkyl ether sulphates, al kylamido ether sulphates, alkylaryl polyether sulphates, monoglyceride sulphates, alkyl sulphonates, alkyl amide sulphonates, alkylarylsulfonates, alpha-olefin sulfonates, paraffin sulfonates, alkylsulfosuccinates, alkylethersulfosuccinates, alkylamide-sulfosuccinates, alkylsulfoacetates, acylsarcosinates, acylglutamates, alkylsulfosuccinamates, acylisethionates and N-acyltaurates, alkyl monoesters and polyglycoside-polycarboxylic acids, acyllactylates, D-galactoside-uronic acid salts, alkyl ether-carboxylic acid salts, alkyl aryl ether-carboxylic acid salts, acid salts. alkyl amidoether carboxylic acids, and the corresponding non-salified forms of all these compounds, alkyl and acyl groups of all these compounds having from 6 to 24 carbon atoms and the aryl group denoting a phenyl group. These compounds may be oxyethylenated and then preferably comprise from 1 to 50 ethylene oxide units. The salts of C 6 -C 24 alkyl monoesters and of polyglycoside-polycarboxylic acids may be chosen from C 6 -C 24 alkyl polyglycoside citrates, C 6 -C 24 alkyl polyglycoside tartrates and polyglycoside sulfosuccinates. of alkyl in 06'024.
[0058] When the agent or the anionic surfactants are in the salt form, they may be chosen from alkali metal salts such as the sodium or potassium salt and preferably sodium salt, ammonium salts, amine salts and in particular aminoalcohols or alkaline earth metal salts such as magnesium salts.
[0059] By way of example of aminoalcohol salts, mention may be made in particular of the salts of mono-, di- and triethanolamine, the salts of mono-, di- or tri-isopropanolamine, the salts of 2-amino-2-methyl-1- propanol, 2-amino-2-methyl-1,3-propanediol and tris (hydroxymethyl) amino methane. The alkali metal or alkaline earth metal salts and in particular the sodium or magnesium salts are preferably used. Among the anionic surfactants mentioned, it is preferred to use (C 6 -C 24) alkyl sulphates, alkyl (C 6 -C 24) ether sulphates comprising from 2 to 50 ethylene oxide units, in particular in the form of alkali metal or ammonium salts. , aminoalcohols, and alkaline earth metals, or a mixture of these compounds.
[0060] In particular, it is preferred to use (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metal salts, ammonium salts, aminoalcohol , and alkaline earth metals, or a mixture of these compounds. More preferably, it is preferred to use sodium lauryl ether sulfate especially those with 2.2 moles of ethylene oxide. More preferentially, (C 12 -C 20) alkylsulfates such as alkali metal laurylsulfate such as sodium. (b) Amphoteric Surfactant (s): The amphoteric or zwitterionic surfactant (s) of the invention are preferably non-silicone, and are in particular derivatives of secondary or tertiary aliphatic amines, optionally quaternized, in which the Aliphatic group is a linear or branched chain having from 8 to 22 carbon atoms, said amine derivatives containing at least one anionic group such as, for example, a carboxylate group, sulfonate, sulfate, phosphate or phosphonate. Mention may in particular be made of (C 8 -C 20) alkyl betaines, sulfobetaines, (C 8 -C 20) alkylamidoalkyl (O-C 8) betaines and (C 8 -C 20) alkylamidalkyl (C 6 -C 8) sulfobetaines. Among the amphoteric or zwitterionic surfactants mentioned above, use is preferably made of alkyl (C 8 -C 20) betaines such as cocobetaine, (C 8 -C 20) alkylamido (C 3 -C 8) alkyl betaines such as cocamidopropylbetaine, and their mixtures. More preferably, the amphoteric or zwitterionic surfactant (s) is (are) chosen from cocamidopropylbetaine and cocobetaine. (c) Cationic surfactant (s): The cationic surfactant (s) that may be used in the composition according to the invention comprise, for example, amine salts. primary, secondary or tertiary fats, optionally polyoxyalkylenated, quaternary ammonium salts, and mixtures thereof. Among the cationic surfactants that may be present in the composition according to the invention, it is more particularly preferred to choose the salts of cetyltrimethylammonium, behenyltrimethylammonium, dipalmethylethylhydroxyethylmethylammonium, and mixtures thereof, and more particularly behenyltrimethylammonium chloride, sodium chloride. cetyltrimethylammonium, dipalmitoylethylhydroxyethylammonium methosulfate, and mixtures thereof. (d) Nonionic surfactant (s): Examples of nonionic surfactants that can be used in the composition used according to the invention are described, for example, in "Handbook of Surfactants" by MR Porter, published by Blackie & Son ( Glasgow and London), 1991, pp 116-178. As examples of nonionic surfactants, mention may be made of: oxyalkylenated (C 8 -C 24) alkyl phenols; saturated or unsaturated, linear or branched, oxyalkylenated or glycerolated C 8 -C 30 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated C 8 -C 30 amides; saturated or unsaturated, linear or branched, C 8 -C 30 acid esters of polyethylene glycols; saturated or unsaturated, linear or branched C 8 -C 30 acid esters of polyoxyethylenated sorbitan; esters of fatty acids and of sucrose - alkyl (C 8 -C 30) polyglycosides, alkenyl (C 8 -C 30) poly-glycosides, optionally oxyalkylenated (0 to 10 oxyalkylenated units) and comprising 1 to 15 glucose units, alkyl (C8-C30) glucosides, vegetable oils oxyethylenated, saturated or not; condensates of ethylene oxide and / or of propylene oxide, inter alia, alone or as mixtures, derivatives of N-alkyl (C 8 -C 30) glucamine and N-acyl (C 8 -C 30) methylglucamine; aldobionamides; amine oxides; Oxyethylenated and / or oxypropylenated silicones; the surfactants having a number of moles of ethylene oxide and / or propylene preferably ranging from 1 to 100, more preferably from 2 to 100 and preferably from 2 to 50, more preferably from 2 to 30. Advantageously, the nonionic surfactants do not comprise oxypropylene units. According to a preferred embodiment of the invention, the nonionic surfactants are chosen from oxyethylenated C 8 -C 30 alcohols comprising from 1 to 100 moles, more particularly from 2 to 100 moles of ethylene oxide; linear or branched, saturated or unsaturated C8-C30 acid esters of polyoxyethylenated sorbitan comprising from 1 to 100 moles, more preferably from 2 to 100 moles of ethylene oxide. By way of example of mono- or poly-glycerolated nonionic surfactants, the C 8 -C 40 mono- or polyglycerolated alcohols are preferably used. In particular, the mono- or poly-glycerolated C 8 -C 40 alcohols preferably correspond to the following formula (A 8): R 2 90 - [CH 2 -CH (CH 2 OH) -O] --H (A 8) Formula (A 8) in which: R29 represents a linear or branched C8-C40, preferably C8-C30, alkyl or alkenyl radical; and - m represents a number ranging from 1 to 30 and preferably from 1 to 10.
[0061] By way of example of compounds of formula (A8) suitable within the scope of the invention, mention may be made of lauryl alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 LAURYL ETHER), lauryl alcohol with 1.5 moles of glycerol, oleic alcohol with 4 moles of glycerol (INCI name: POLYGLYCERYL-4 OLEYL ETHER), oleic alcohol with 2 moles of glycerol (INCI name: POLYGLYCERYL-2 OLEYL ETHER), alcohol cetearyl to 2 moles of glycerol, cetearyl alcohol to 6 moles of glycerol, oleocetyl alcohol to 6 moles of glycerol, and octadecanol to 6 moles of glycerol. The alcohol of formula (A8) may represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that in a commercial product several species of polyglycerolated fatty alcohols may coexist in the form of a mixed. Among the mono- or poly-glycerolated alcohols, it is more particularly preferred to use the C 8 / C 10 alcohol with one mole of glycerol, the C 10 / C 12 alcohol with 1 mole of glycerol and the alcohol with C 12 at 1.5 mole of glycerol.
[0062] Preferably, the nonionic surfactant used in the process of the invention in the composition is a mono or polyoxyalkylene nonionic surfactant, especially mono or polyoxyethylenated, mono or polyoxypropylenated, or their combination, more particularly mono or polyoxyethylenes, mono- or polyglycerolated surfactants and alkylpolyglucosides. Even more preferentially, the nonionic surfactants are chosen from polyoxyethylenated sorbitan esters, polyoxyethylenated fatty alcohols, alkylpolyglucosides and their mixtures. The surfactant (s) when they are (are) present, represent (s) more particularly 0.01% and 60% by weight relative to the total weight of the composition (s) (s) ) included in the packaging article, preferably between 0.5% and 30% by weight and even more preferably between 1% and 20% by weight of the composition (s) included in the 'Article packaging.
[0063] According to a particular embodiment, the packaging article of the invention comprises viii) one or more cationic or amphoteric substantive polymers. The latter may be in said article either with the anhydrous chemical oxidizing agent (s) or separated from the other ingredients by one or more water-soluble layers as defined above, which define a cavity in which the substantive polymer (s) is housed. Preferably ix) are found with the oxidizing agents in the packaging article. More particularly, the substantive polymers are chosen from cationic polymers. The substantive character (ie the hair depositability) of the polymers is conventionally determined by means of the test described by Richard J. Crawford, Journal of the Society of Cosmetic Chemists, 1980, 31 - (5) - pages 273-278 (disclosure by Red 80 acid dye). These substantive polymers are in particular described in the literature in the patent application EP-A-0557203. Among the substantive polymers of the dimethyldiallylammonium halide homopolymer or copolymer type that may be used according to the invention, mention may be made in particular of: - diallyldimethylammonium chloride polymers such as polyquaternium-6 - copolymers of diallyldimethylammonium chloride and of acrylic acid as that of proportions (80/20 by weight) sold under the name Merquat 280 dry by Calgon; copolymers of dimethyldiallylammonium chloride and acrylamide. Among the polymeric polymers of the methacryloyloxyethyltrimethylammonium halide polymer type that may be used according to the invention, mention may be made in particular of the products which are named in the CTFA dictionary (5th edition, 1993) "Polyquaternium 37", "Polyquaternium 32" and "Polyquaternium" 35 ", which respectively correspond, as regards" Polyquaternium 37 ", to the cross-linked poly (methacryloyloxyethyltrimethylammonium) chloride, in a 50% dispersion in mineral oil, and sold under the name Salcare SC95 by the company Allied Colloids, as regards "Polyquaternium 32", to the crosslinked copolymer of acrylamide and methacryloyloxyethyltrimethylammonium chloride (20/80 by weight), in a 50% dispersion in mineral oil, and sold under the name Salcare SC92 by the company Allied Colloids, and as regards the "Polyquaternium 35", with the methosulfate of the methacryloyloxyethyltrimethylammonium copolymer onium and methacryloyloxyethyldimethylacetylammonium.
[0064] The substantive polymers of the polyammonium quaternary type that may be used according to the invention are the following: polymers consisting of repeating units corresponding to the following formula (a): - (CH 3) 2 N + - (CH 2) 3 - (CH 3) 2 N + - (CH 2 ) 6, 2X- with X-, identical or different, representing an anionic counterion as defined above, in particular halide such as gold, these polymers are prepared and described in French Patent 2,270,846; recurring units of formula (a) whose molecular weight, determined by gel permeation chromatography, is between 9500 and 9900; polymers consisting of repeating units corresponding to the following formula ([3): - (CH 3) 2 N + - (CH 2) 3 - (CH 3) 2 N + - (CH 2) 3, 2X- with X - as defined for (a) ), these polymers are prepared and described in French Patent 2,270,846, recurring patterned polymers of formula ([3), the molecular weight of which, determined by gel permeation chromatography, is about 1200; the polymers consisting of repeating units corresponding to the following formula (y): - (CH 3) 2 N + - (CH 2) pN (H) -C (O) -GN (H) - (Cl-12) p- (Cl- 13) 2N + - (CH2) 2-O- (C1-12) 2-, 2X- wherein p denotes an integer ranging from 1 to about 6, G may represent a bond or a group - (Cl-12), -C (O) - wherein r denotes an integer of 4 or 7, these polymers are prepared and described in US Pat. Nos. 4,157,388, 4,390,689, 4,702,906, 4,719,282, polymers are preferred. with recurring units of formula (y), the molecular weight of which has a molecular mass of less than 100,000, preferably less than or equal to 50,000. The packaging article of the invention may also comprise other conventionally used additives. in cosmetics. The packaging article may thus comprise particular fillers such as clays, hydrophilic or hydrophobic silicas; binders such as vinylpyrrolidone; lubricants such as polyol stearates or stearates of alkali or alkaline earth metals; ; pigments; direct dyes; mattifying or opacifying agents such as titanium oxides; antioxidants such as erythorbic acid; reducing agents such as sodium metabisulfite; penetrating agents, sequestering agents, such as ethylenediamine tetraacetic or its salts; moisture-absorbing agents such as amorphous silicas, certain polyacrylates crosslinked or modified with hydrophobic groups such as, for example, Luquasorb 1010 products from BASF, Polytrap 6603 Adsorber from AMCOL; buffers; dispersants; film-forming agents; preservatives; vitamins ; perfumes ; ceramides, conditioning agents other than the substantive polymers ix) and cationic surfactants mentioned above. The composition according to the invention may also comprise agents for controlling the release of oxygen such as carbonate or magnesium oxide. The additives and oxygen release control agents as defined above may be present in an amount for each of them ranging from 0.01 to 40% by weight, preferably from 0.1 to 30% by weight relative to to the total weight of the composition or article.
[0065] Another object of the invention relates to a method for treating keratinous fibers, in particular a method for dyeing or bleaching keratin fibers using the article as defined according to the invention. In particular, another subject of the invention is a process for treating keratinous fibers, in particular a process for dyeing or bleaching keratinous fibers such as the hair, comprising at least the following steps: i) mixing the packaging article as defined above in a composition capable of solubilizing the envelope of the packaging article, ii) applying the resulting composition to the keratinous fibers, iii) allowing pausing, iv) rinsing said fibers, v) optionally shampooing the fibers, rinse and dry. It is of course understood that according to the nature of the envelope, the composition capable of solubilizing the envelope will be water or an aqueous composition when the envelope contains predominantly or only a hydrophilic envelope, and the composition capable of solubilizing the envelope will be an organic composition comprising a liquid, anhydrous or aqueous fatty substance, when the article contains mainly or only lipophilic sheets and envelopes. Thus, the aqueous composition may simply be water. The aqueous composition may optionally comprise at least one organic polar solvent. Among the polar organic solvents that may be used in this composition, mention may be made of organic compounds which are liquid at room temperature (25 ° C.) and at least partially miscible with water. By way of example, mention may be made more particularly of alkanols such as ethyl alcohol, isopropyl alcohol, aromatic alcohols such as benzyl alcohol, and phenylethyl alcohol, or polyols or polyol ethers such as for example, ethylene glycol monomethyl, monoethyl and monobutyl ethers, propylene glycol or its ethers such as, for example, propylene glycol monomethyl ether, butylene glycol, dipropylene glycol and diethylene glycol alkyl ethers such as, for example, monoethyl ether or methylenediamine. monobutyl ether diethylene glycol. More particularly, if one or more solvents are present, their respective content in the aqueous composition ranges from 0.5 to 20% and preferably from 2 to 10% by weight relative to the weight of said aqueous composition.
[0066] According to one embodiment, the process as defined above uses, in the first step, an aqueous composition which optionally comprises at least one basifying agent iii) as defined previously or optionally at least one ingredient chosen from: ammonium salts iv), preferably selected from ammonium halides such as ammonium chloride, ammonium sulfate, ammonium phosphate and ammonium nitrate; the liquid fatty substances v) preferably chosen from mineral oils, in particular liquid petrolatum; thickening polymers vi); the surfactants viii), preferably nonionic or anionic, in particular chosen from (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metals, ammonium, aminoalcohols, and alkaline earth metals, or a mixture of these compounds; preferably (C 12 -C 20) alkylsulfates such as alkali metal laurylsulfate such as sodium; and the substantive cationic or amphoteric polymers ix) as defined above.
[0067] These optional additives may be present in the packaging article. According to another particular variant of the invention, the composition capable of solubilizing the envelope is an aqueous composition comprising a chemical oxidizing agent, preferably hydrogen peroxide, and optionally at least one basifying agent iii) or at least one ingredient as defined in the preceding variant, these alkaline agents and these ingredients possibly being present in the packaging article. The weight concentration of hydrogen peroxide may be from 2 to 12%, preferably from 2 to 6% by weight of the aqueous composition.
[0068] Preferentially, the process as defined above is such that the dilution ratio of one or more conditioning article (s) as defined above / the composition capable of solubilizing the article or articles, expressed by weight, is included between 10/90 and 90/10, preferably between 10/90 and 50/50. Preferably, this ratio is 20/80. When the composition capable of solubilizing the article is an aqueous composition comprising hydrogen peroxide, it preferably has a pH of less than 7.
[0069] The acidic pH guarantees the stability of the hydrogen peroxide in the composition. It can be obtained using acidifying agents such as, for example, hydrochloric acid, acetic acid, ethydronic acid, phosphoric acid, lactic acid or boric acid, and it can be adjusted conventionally by adding either alkalizing agents, as defined above, all these compounds can of course be taken alone or in mixture.
[0070] The pH of the resulting mixture is usually between 7 and 12 inclusive. Preferably, the pH of said is usually between 7.5 and 11 inclusive. Once the mixture is made to obtain the ready-to-use composition, it is applied on human keratin fibers, dry or wet.
[0071] The pause time is generally of the order of 1 minute to 1 hour, preferably 10 minutes to 30 minutes. The operating temperature of the process is conventionally between room temperature (between 15 and 25 ° C.) and 80 ° C., preferably between room temperature and 60 ° C.
[0072] At the end of the treatment, the human keratinous fibers are optionally rinsed with water, washed with shampoo, rinsed again with water and then dried or left to dry. The following examples serve to illustrate the invention without, however, limiting its scope. EXAMPLES Example 1. The following compositions were prepared. The values are expressed in gram (s) of active material for a total composition of 100 grams.
[0073] Composition A Sorbitol 17 Ammonium sulphate 5 Sodium carbonate peroxide or Na percarbonate 50 Sodium metasilicate 7.5 Vaseline oil 4 Carboxymethylcellulose Sodium salt 5 Hydroxyethylcellulose 7.5 Sodium lauryl sulfate 1 Nonwoven polyvinyl alcohol fiber ( PVA) of 3 average diameter of about 10 microns Il) Protocol for preparing the compositions and the packaging article The packaging article is prepared in two stages, firstly the ingredients are selected. The mixture of the powdered ingredients is then homogenized. In a second step, the envelope is prepared from PVA which are in the form of two nonwoven webs joined to each other at the periphery but leaving an open part allowing the introduction of ingredients. This double layer is in the form of a disc (diameter 5 cm and thickness of 3 mm). The mixture of said powdered ingredients is then introduced between the two sheets of PVA of the disc, then the open part is closed.
[0074] An article comprising composition A in the form of a single dose of 21.6 g is prepared according to the mode indicated above. At the time of use, the article is mixed with 78.4 grams of tap water. The mixture is applied to pigmented natural hair with a pause time of between 5 minutes and 1 hour and preferably between 10 minutes and 40 minutes. The hair is rinsed and then shampooed and preferably shampooed and the hair dried. Example 2 Composition B1 B2 Potassium persulfate 27.42 27.42 Hydroxypropylcellulose 0.91 0.91 PVP / H202 complex (PEROXYDONE XL-10 32.49 Ashland) Sodium Carbonate Peroxide or 32.49 Na Percarbonate Ammonium Chloride 2.91 2.91 Sodium Metasilicate 9.32 9.32 Non-woven Polyvinyl alcohol Fibers ( PVA) 26.95 26.95 average diameter of about 10 microns The compositions B1 and B2 are prepared in the following manner: First, the powder ingredients are selected, the peroxygenated salts, the alkaline agents and the other agents chemical oxidants. The mixture of the powdered ingredients is then homogenized. The PVA fibers (26.95 g for 73.05 g of bleaching pulverulent composition) are in the form of two nonwoven webs joined to each other at the periphery but leaving an open part allowing the introduction of ingredients. This double layer is in the form of a disc (diameter 5 cm and thickness of 3 mm). The mixture of said non-PVA powder ingredients is then introduced between the two sheets of PVA of the disc, and then the open part is closed again.
[0075] Articles comprising each composition B1 and B2 in the form of a single dose of 21.6 g are prepared according to the mode indicated above. At the time of use, each article is mixed with 78.4 g of water. The mixture is applied to pigmented natural hair with a pause time of between 5 minutes and 1 hour and preferably between 10 minutes and 40 minutes. We rinse the hair and then we do or not shampoo and preferably we shampoo and then dry hair. The locks of pigmented hair are brightened from 1 to 2.5 shades depending on the starting hair (2.5 shades for natural brown hair). In addition the application and location is easy compositions is very nice and does not leave the areas to be treated. It should be noted that the process is very easy to implement since it involves solubilizing the packaging article. This gives a good discoloration of the hair with great ease of use.

权利要求:
Claims (23)
[0001]
REVENDICATIONS1. A packaging article comprising: i) an envelope defining at least one cavity, the shell comprising water-soluble and / or fat-soluble fibers, preferably water-soluble fibers; ii) at least one anhydrous oxidizing composition, preferably in the form of a paste or a powder, comprising at least one anhydrous chemical oxidizing agent, preferably in the form of a paste or a powder; it being understood that the oxidizing composition is in one of the cavities defined by the envelope i).
[0002]
2. Article according to the preceding claim wherein the anhydrous oxidizing composition is in the form of paste or powder.
[0003]
3. Article according to claim 1 or 2 wherein the envelope i) comprises predominantly water-soluble polymer fibers. ,
[0004]
4. Article according to any one of the preceding claims wherein the envelope i) comprises water-soluble polymer fibers, natural, artificial or synthetic, preferably chosen from polyvinyl alcohol (PVA) fibers, polysaccharide fibers, polyester fibers. polylactic acid, and polyalkylene oxide fibers, as well as their mixture.
[0005]
5. Article according to any one of the preceding claims wherein the envelope i) comprises water-soluble polymer fibers selected from polysaccharides particularly selected from glucomannans, starches, alginates, and celluloses and preferably carboxymethyl starch.
[0006]
6. Article according to any preceding claim wherein the envelope i) comprises synthetic water-soluble polymer fibers, preferably selected from PVA fibers.
[0007]
7. Article according to any one of the preceding claims wherein the envelope i) is a nonwoven.
[0008]
8. Article according to claims 1 to 7 wherein the envelope i) comprises liposoluble polymer fibers.
[0009]
9. Article according to any one of the preceding claims wherein the envelope i) comprises spun fibers, carded or twisted, and of diameter, identical or different, less than 500 pm; preferably less than 200 μm, preferably less than 100 μm, or even less than 50 μm and / or the tensile strength of said fibers is at least 2.7 g / dtex (3 g / d).
[0010]
10. Article according to any one of the preceding claims wherein the envelope i) represents an amount included between 0.5% and 20.0% by weight relative to the total weight of said article; advantageously between 1.0% and 10.0%, particularly between 2.0% and 5.0%; more particularly 3% by weight relative to the total weight of the packaging article.
[0011]
11.Article according to any one of the preceding claims wherein the chemical oxidizing agent is chosen from peroxygenated salts such as persulfates, perborates, peracids and their precursors, alkali metal or alkaline earth percarbonates such as peroxide. sodium carbonate or sodium percarbonate; alkali metal bromates or ferricyanides, solid hydrogen peroxide-generating oxidizing agents such as urea peroxide and polymeric complexes capable of releasing hydrogen peroxide, especially those comprising a vinyl heterocyclic monomer such as polyvinylpyrrolidone complexes; H202 in particular being in the form of powders; oxidases producing hydrogen peroxide in the presence of a suitable substrate (for example glucose in the case of glucose oxidase or uric acid with uricase), and mixtures thereof.
[0012]
12. Article according to any one of the preceding claims wherein the anhydrous chemical oxidizing agent is selected from peroxygenated salts, preferably from persulfates, alkali metal or alkaline earth metal percarbonates such as sodium carbonate peroxide, complexes polyvinylpyrrolidone / H 2 O 2, and mixtures thereof.
[0013]
13. Article according to any one of the preceding claims, which comprises at least alkaline agent iii), preferably mineral preferably selected from water-soluble silicates such as alkali or alkaline-earth metal silicates, alkali metal basic or tribasic phosphates. or alkaline-earth metals or alkali or alkaline-earth metal carbonates, and mixtures thereof.
[0014]
14. Article according to any preceding claim which comprises at least one ingredient selected from: ammonium salts iv), in particular selected ammonium halides such as ammonium chloride, ammonium sulfate, phosphate ammonium and ammonium nitrate and mixtures thereof; the fatty substances, preferably liquid, v) preferably chosen from mineral oils, in particular liquid petroleum jelly; thickening polymers vi); the surfactants vii), preferably nonionic or anionic, in particular chosen from (C 12 -C 20) alkyl sulphates, C 12 -C 20 alkyl ether sulphates comprising from 2 to 20 ethylene oxide units, in particular in the form of alkali metals, ammonium, aminoalcohols, and alkaline earth metals, or a mixture of these compounds; preferably (C 12 -C 20) alkylsulfates such as alkali metal laurylsulfate such as sodium; and cationic or amphoteric substantive polymers viii).
[0015]
15. Packaging article according to any one of the preceding claims wherein the envelope i) consists of two water-soluble or liposoluble (11, 12), preferably water-soluble, layers joined together at a peripheral region (14), preferably the two plies being joined by any suitable fastening means such as gluing, welding including heat sealing, in particular by entanglement; the first ply (11) further has a free central region (D) disposed facing a free central region (D) of the second ply 12; these two central regions defining a central cavity, said central cavity containing an anhydrous oxidizing composition (13) comprising at least one anhydrous chemical oxidizing agent as defined in any one of claims 1 or 11 and 12, optionally mixed with other ingredients such as as defined in any of claims 14 and 15; the plies (11, 12) have an outer periphery (15) closed whose shape is for example rounded, such as circular or elliptical, or polygonal, such as square, rectangular, triangular; preferably circular.
[0016]
16. Packaging article according to the preceding claim which further comprises a web (16), preferably water-soluble, and optionally other (s) water-soluble (s) or additional liposoluble (s) (17). ), preferably water-soluble (s) which define one or more cavities, separating the anhydrous oxidizing composition (18) as defined in claim 1 from the other ingredients (19) or (20) as defined in any one of claims 14 and 15.
[0017]
17. Packaging article according to claims 15 or 16, the first sheet (11) preferably water-soluble, the second sheet (12) preferably water-soluble, and optionally the additional sheets (16) and (17), preferably water-soluble, have a thickness less than their other dimensions, in particular less than 10% of their maximum transverse dimensions D + 2d; preferably, the thickness of the first preferably water-soluble sheet (11) and the second preferably water-soluble sheet being in particular less than 10 mm and in particular between 0.1 mm and 3 mm and their maximum transverse dimensions D + 2d being less than at 100 mm, and being included inclusive between 10 mm and 60 mm.
[0018]
18. Packaging article according to any one of claims 15 to 17, the first sheet (11) preferably water-soluble, is a nonwoven and the second web (12) preferably water-soluble is a nonwoven and also has an outer periphery 15 closed; the outer periphery (15) of the first layer (11) is substantially identical in shape to the outer periphery (15) of the second layer (12).
[0019]
19. A process for treating keratinous fibers, in particular human fibers such as the hair, comprising the following steps: i) mixing the packaging article as defined in any one of claims 1 to 18 in a composition capable of solubilizing the article of conditioning, ii) applying the resulting composition to the keratin fibers, iii) pausing, iv) rinsing said fibers, v) optionally shampooing the fibers, rinsing and drying them.
[0020]
20. The method of claim 19 wherein the composition capable of solubilizing the article is an aqueous composition or an organic composition comprising at least one liquid fatty substance.
[0021]
21. The method of claim 19 or 20 wherein the composition capable of solubilizing the article comprises a chemical oxidizing agent, preferably hydrogen peroxide.
[0022]
22. Method according to one of claims 19 to 21 wherein the composition capable of solubilizing the packaging article is an aqueous composition comprising a chemical oxidizing agent, preferably hydrogen peroxide.
[0023]
23. Method according to one of claims 19 to 22 wherein the dilution ratio of the packaging / articles / composition capable of solubilizing the packaging articles or articles; ratio expressed by weight, is included between 10/90 and 50/50, preferably 20/80 10

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FR3037795A1|2016-12-30|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND ANHYDROUS COLORING, COLORING OR OXIDIZING COMPOSITION COMPRISING A FIBROUS CLAY, AND A COMPOUND SELECTED FROM A COLORING AGENT AND / OR OXIDIZING AGENT; USE AND METHOD FOR COLORING AND / OR DECOLORIZING KERATIN FIBERS

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EP2413880B1|2015-05-06|Capillary composition for treating hair

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FR3060333A1|2018-06-22|ANHYDROUS SOLID COMPOSITION FOR COLORING KERATIN FIBERS COMPRISING METABISULPHITE

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EP1893294A1|2008-03-05|Capillary cosmetic method comprising a step for the application of a cross-linked polyrotaxane, capillary compositions containing a cross-linked polyrotaxane, and uses thereof

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FR3037793A1|2016-12-30|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND A COLORING, COLORLESS, AND / OR OXIDIZING ANHYDROUS COMPOSITION COMPRISING AT LEAST TWO COMPOUNDS SELECTED FROM A STARCH, A CLAY, AND A CELLULOSE, AND A COMPOUND SELECTED FROM A COLORING AGENT AND / OR AN OXIDIZING AGENT; USE AND METHOD FOR COLORING AND / OR DECOLORIZING KERATIN FIBERS

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FR3037792A1|2016-12-30|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND A COLORING, DECOLORIZING AND / OR OXIDIZING ANHYDROUS COMPOSITION COMPRISING A MODIFIED STARCH, AND A COMPOUND SELECTED FROM A COLORING AGENT AND / OR OXIDIZING AGENT; USE AND METHOD FOR COLORING AND / OR DECOLORIZING KERATIN FIBERS

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FR3089794A1|2020-06-19|Solid composition for coloring or lightening keratin fibers comprising a phospholipid

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WO2005034893A1|2005-04-21|Cosmetic compositions containing an aminated silicone and a thickening agent with at least one sugar moiety and use therof

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FR3102362A1|2021-04-30|ALKALINE COMPOSITION COMPRISING AT LEAST THREE DIFFERENT ALKALINE AGENTS FOR THE TREATMENT OF KERATINIC FIBERS, METHODS AND USES

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FR3037791A1|2016-12-30|PACKAGING ARTICLE COMPRISING AN ENVELOPE CONSISTING OF AT LEAST ONE FILM AND A COLORING, COLORLESS OR OXIDIZING COMPOSITION ANHYDROUS

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FR2994838A1|2014-03-07|Cosmetic composition, useful for cleaning/conditioning keratin materials such as hair, comprises modified/unmodified starches, low density hollow type organic particles insoluble in water, amphoteric polymers, and antidandruff agents

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FR3075611A1|2019-06-28|PROCESS FOR THE TREATMENT OF KERATIN FIBERS USING A FLUORESCENCE HALOCHROME DIRECT DYE, ALKALINE DEVELOPER THEN ACIDIC CLEANER

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FR3075616A1|2019-06-28|PROCESS FOR TREATING KERATINOUS FIBERS USING DIRECT OXAZONE OR PHENAZINE HALOCHROME COLOR, DEVELOPER THEN ERASER

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FR2940068A1|2010-06-25|Composition, useful for e.g. cleaning keratin materials, comprises anionic surfactants, carboxylic anionic surfactants, amphoteric and/or zwitterionic surfactants, alkyl|glycoside nonionic surfactants, cationic polymers, and filters

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FR3003464A1|2014-09-26|COSMETIC COMPOSITION COMPRISING HOLLOW OR POROUS PARTICLES, MONOALCOOL AND THICKENING POLYMER, METHODS OF COSMETIC TREATMENT AND USES

同族专利:

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公开号 | 公开日

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EP3086857B1|2017-11-15|

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FR3016288B1|2016-09-09|

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ES2654687T3|2018-02-14|

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US20210046333A1|2021-02-18|

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US20170007856A1|2017-01-12|

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EP3086857A1|2016-11-02|

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WO2015097101A1|2015-07-02|

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CN105828883A|2016-08-03|

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US2120317A|1935-09-30|1938-06-14|Victor A Strom|Paper packet|

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WO1991001127A1|1989-07-21|1991-02-07|Brooks Geoffrey J|Method of bleaching and conditioning hair, bleach packet and bleaching solutions|

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CA2520015A1|2003-03-22|2004-09-30|Henkel Kommanditgesellschaft Auf Aktien|Mixing device|

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US20070134481A1|2005-12-07|2007-06-14|L'oreal|Soluble patch|

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BRPI0907074A2|2008-12-19|2013-05-07|Oreal|keratin fiber bleaching or coloring process, anhydrous composition and multi-compartment device|FR3015231B1|2013-12-23|2017-02-24|Oreal|PACKAGING ARTICLE COMPRISING AN ENVELOPE ANHYDROUS COLORING COMPOSITION COMPRISING A DIRECT COLOR, USE AND METHOD FOR COLORING KERATINIC FIBERS|

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FR3015232B1|2013-12-23|2016-01-08|Oreal|PACKAGING ARTICLE COMPRISING AN ENVELOPE ANHYDROUS COLORING COMPOSITION COMPRISING AN OXIDATION COLOR, USE AND METHOD FOR COLORING KERATIN FIBERS|

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FR3037792B1|2015-06-25|2017-06-23|Oreal|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND A COLORING, DECOLORIZING AND / OR OXIDIZING ANHYDROUS COMPOSITION COMPRISING A MODIFIED STARCH, AND A COMPOUND SELECTED FROM A COLORING AGENT AND / OR OXIDIZING AGENT; USE AND METHOD FOR COLORING AND / OR DECOLORIZING KERATIN FIBERS|

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FR3037795B1|2015-06-25|2018-08-17|L'oreal|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND ANHYDROUS COLORING, COLORING OR OXIDIZING COMPOSITION COMPRISING A FIBROUS CLAY, AND A COMPOUND SELECTED FROM A COLORING AGENT AND / OR AN OXIDIZING AGENT; USE AND METHOD FOR COLORING AND / OR DECOLORIZING KERATIN FIBERS|

---

FR3037793B1|2015-06-25|2018-07-13|L'oreal|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND A COLORING, COLORLESS, AND / OR OXIDIZING ANHYDROUS COMPOSITION COMPRISING AT LEAST TWO COMPOUNDS SELECTED FROM A STARCH, A CLAY, AND A CELLULOSE, AND A COMPOUND SELECTED FROM A COLORING AGENT AND / OR AN OXIDIZING AGENT; USE AND METHOD FOR COLORING AND / OR DECOLORIZING KERATIN FIBERS|

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WO2019051441A1|2017-09-11|2019-03-14|Liqwd, Inc.|Containers for forming hair bleaching formulations|

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DE102017222124A1|2017-12-07|2019-06-13|Henkel Ag & Co. Kgaa|Percarbonate in a water-soluble film for bleaching human hair|

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DE102018133663A1|2018-12-28|2020-07-02|Henkel Ag & Co. Kgaa|Thickener in a bleaching agent containing percarbonate contained in a multilayer sachet|

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DE102019105176A1|2018-12-28|2020-07-02|Henkel Ag & Co. Kgaa|Powder hair color with percarbonate in a water-soluble film|

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EP3864997A1|2020-02-14|2021-08-18|Cosmar Consulting S.A.S. di Lucio Mariotti|Biocompatible container for cosmetic products|

法律状态:
2015-11-10| PLFP| Fee payment|Year of fee payment: 3 |

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2016-11-11| PLFP| Fee payment|Year of fee payment: 4 |

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2017-11-13| PLFP| Fee payment|Year of fee payment: 5 |

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2018-11-20| PLFP| Fee payment|Year of fee payment: 6 |

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2020-10-16| ST| Notification of lapse|Effective date: 20200910 |

优先权:

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申请号 | 申请日 | 专利标题

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FR1363394A|FR3016288B1|2013-12-23|2013-12-23|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND ANHYDROUS COMPOSITION COMPRISING AN OXIDIZING AGENT|FR1363394A| FR3016288B1|2013-12-23|2013-12-23|PACKAGING ARTICLE COMPRISING AN ENVELOPE AND ANHYDROUS COMPOSITION COMPRISING AN OXIDIZING AGENT|

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CN201480070533.5A| CN105828883A|2013-12-23|2014-12-19|Process for treating keratin fibers using a packaging article comprising an envelope and an anhydrous composition comprising an oxidizing agent|

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EP14815760.5A| EP3086857B1|2013-12-23|2014-12-19|Process for treating keratin fibers using a packaging article comprising an envelope and an anhydrous composition comprising an oxidizing agent|

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PCT/EP2014/078855| WO2015097101A1|2013-12-23|2014-12-19|Process for treating keratin fibers using a packaging article comprising an envelope and an anhydrous composition comprising an oxidizing agent|

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ES14815760.5T| ES2654687T3|2013-12-23|2014-12-19|Process for treating keratin fibers using a packaging article comprising a wrapper and an anhydrous composition comprising an oxidizing agent|

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US15/107,319| US20170007856A1|2013-12-23|2014-12-19|Process for treating keratin fibers using a packaging article comprising an envelope and an anhydrous composition comprising an oxidizing agent|

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US16/861,380| US20210046333A1|2013-12-23|2020-04-29|Process for treating keratin fibers using a packaging article comprising an envelope and an anhydrous composition comprising an oxidizing agent|